Ga2o3-based semiconductor device

ABSTRACT

A Ga 2 O 3 -based semiconductor device includes a Ga 2 O 3 -based crystal layer including a donor, and an N-doped region formed in at least a part of the Ga 2 O 3 -based crystal layer.

TECHNICAL FIELD

The invention relates to a Ga₂O₃-based semiconductor device.

BACKGROUND ART

A technique of epitaxially growing an undoped (not containing intentionally doped dopant) Ga₂O₃-based crystal film on a Ga₂O₃-based substrate is conventionally known (e.g., Patent Literature 1).

A semiconductor device, which has an underlying substrate formed of a Ga₂O₃-based crystal, a buffer layer epitaxially grown on the underlying substrate and formed of an undoped Ga₂O₃-based crystal, and a Ga₂O₃-based crystal layer formed on the buffer layer and containing Si doped as a dopant, is also conventionally known (see, e.g., Non-Patent Literature 1).

CITATION LIST Patent Literature

Patent Literature 1: JP 2017-041593 A

Non-Patent Literature

Non-Patent Literature 1: Man Hoi Wong, et al., “Anomalous Fe diffusion in Si-ion-implanted β-Ga₂O₃ and its suppression in Ga₂O₃ transistor structures through highly resistive buffer layers”, Applied Physics Letters 106, 032105, 2015

SUMMARY OF INVENTION Technical Problem

Ga₂O₃-based crystal film, when epitaxially grown without doping, sometimes becomes n-type due to an unintentional donor. In case that such undoped Ga₂O₃-based crystal film is used in a semiconductor device, a problem may occur due to the undoped Ga₂O₃-based crystal film which became n-type.

For example, in case of FET (Field effect transistor) in which an undoped Ga₂O₃-based crystal film is used as a buffer layer, the FET fails to operate normally since a current also flows through the buffer layer (leakage current) in addition to through the channel layer.

For this reason, it is sometimes required to add an appropriate acceptor to the undoped Ga₂O₃-based crystal layer so that the unintentionally doped donor is compensated and resistance is increased. In case of an impurity which acts as an acceptor in the Ga₂O₃-based crystal layer, it can be also used to form a p-type region in the undoped Ga₂O₃-based crystal layer or in the n-type undoped Ga₂O₃-based crystal layer.

It is an object of the invention to provide a Ga₂O₃-based semiconductor device which has a Ga₂O₃-based crystal layer doped with a novel acceptor impurity.

Solution to Problem

To achieve the above-mentioned object, an aspect of the invention provides a Ga₂O₃-based semiconductor device according to [1] to [8] below.

[1] A Ga₂O₃-based semiconductor device, comprising a Ga₂O₃-based crystal layer comprising a donor, and an N (nitrogen)-doped region formed in at least a part of the Ga₂O₃-based crystal layer.

[2] The Ga₂O₃-based semiconductor device according to [1], wherein the N-doped region comprises N at a higher concentration than the donor.

[3] The Ga₂O₃-based semiconductor device according to [1] or [2], wherein the N-doped region is formed in a part of the Ga₂O₃-based crystal layer.

[4] The Ga₂O₃-based semiconductor device according to [1], wherein the donor is unintentionally doped to the Ga₂O₃-based crystal layer, and the N-doped region comprises N at a concentration not more than the concentration of the donor.

[5] The Ga₂O₃-based semiconductor device according to any one of [1], [2] and [4], comprising a vertical Schottky barrier diode in which the N-doped region is a current path or a guard ring.

[6] The Ga₂O₃-based semiconductor device according to [1] or [2], comprising a vertical MOSFET in which the N-doped region comprises a channel region or is a current blocking region comprising an opening region as a current path.

[7] The Ga₂O₃-based semiconductor device according to any one of [1], [2] and [4], comprising a lateral MOSFET in which the N-doped region comprises a channel region or is located between a channel region in the Ga₂O₃-based crystal layer and a bottom surface of the Ga₂O₃-based crystal layer.

[8] The Ga₂O₃-based semiconductor device according to any one of [1], [2] and [4], comprising a MESFET in which the N-doped region comprises a channel region or is located between a channel region in the Ga₂O₃-based crystal layer and a bottom surface of the Ga₂O₃-based crystal layer.

Advantageous Effects of Invention

According to the invention, it is possible to provide a Ga₂O₃-based semiconductor device which has a Ga₂O₃-based crystal layer doped with a novel acceptor impurity.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a vertical cross-sectional view showing a Schottky barrier diode in the first embodiment.

FIG. 2 is a vertical cross-sectional view showing a Schottky barrier diode in the first embodiment.

FIG. 3 is a vertical cross-sectional view showing a Schottky barrier diode in the first embodiment.

FIG. 4 is a vertical cross-sectional view showing a vertical MOSFET in the second embodiment.

FIG. 5 is a vertical cross-sectional view showing a vertical MOSFET in the second embodiment.

FIG. 6 is a vertical cross-sectional view showing a vertical MOSFET in the second embodiment.

FIG. 7 is a vertical cross-sectional view showing a lateral MOSFET in the third embodiment.

FIG. 8 is a vertical cross-sectional view showing a lateral MOSFET in the third embodiment.

FIG. 9 is a vertical cross-sectional view showing a lateral MOSFET in the third embodiment.

FIG. 10 is a vertical cross-sectional view showing a lateral MOSFET in the third embodiment.

FIG. 11 is a vertical cross-sectional view showing a MESFET in the fourth embodiment.

FIG. 12 is a vertical cross-sectional view showing a MESFET in the fourth embodiment.

FIG. 13 is a vertical cross-sectional view showing a sample device used in experiments in Example 1.

FIG. 14 is a graph showing measured leakage characteristics of the sample device.

FIG. 15A is a SIMS depth profile of N density in a second Ga₂O₃-based crystal layer when a N₂ gas concentration in an O₂—N₂ gas mixture used for growth of the second Ga₂O₃-based crystal layer is 0 vol %.

FIG. 15B is a SIMS depth profile of N density in the second Ga₂O₃-based crystal layer when the N₂ gas concentration in the O₂—N₂ gas mixture used for growth of the second Ga₂O₃-based crystal layer is 0.04 vol %.

FIG. 15C is a SIMS depth profile of N density in the second Ga₂O₃-based crystal layer when the N₂ gas concentration in the O₂—N₂ gas mixture used for growth of the second Ga₂O₃-based crystal layer is 0.4 vol %.

FIG. 16A is a graph showing electrical conduction properties of the Schottky barrier diode when the N₂ gas concentration in the O₂—N₂ gas mixture used for growth of the second Ga₂O₃-based crystal layer is 0 vol %.

FIG. 16B is a graph showing electrical conduction properties of the Schottky barrier diode when the N₂ gas concentration in the O₂—N₂ gas mixture used for growth of the second Ga₂O₃-based crystal layer is 0.04 vol %.

FIG. 16C is a graph showing electrical conduction properties of the Schottky barrier diode when the N₂ gas concentration in the O₂—N₂ gas mixture used for growth of the second Ga₂O₃-based crystal layer is 0.4 vol %.

FIG. 17 is a graph showing a relation between the N₂ gas concentration in the O₂—N₂ gas mixture used for growth of the second Ga₂O₃-based crystal layer and forward current density when an anode voltage of the Schottky barrier diode is 6V.

DESCRIPTION OF EMBODIMENTS First Embodiment

The first embodiment is an embodiment of a Schottky barrier diode as a semiconductor device having a Ga₂O₃-based crystal layer in which an N-doped region is formed.

It has not been known that N (nitrogen) can be incorporated into Ga₂O₃-based crystal at a concentration high enough to affect the characteristics, and obviously, it has not been known that N acts as an acceptor in the Ga₂O₃-based crystal.

Ga₂O₃-based single crystal here means a Ga₂O₃ single crystal or is a Ga₂O₃ single crystal doped with an element such as Al or In, and may be, e.g., a (Ga_(x)Al_(y)In_((1-x-y)))₂O₃ (0<x≤1, 0≤y<1, 0<x+y≤1) single crystal which is a Ga₂O₃ single crystal doped with Al and In. The band gap is widened by adding Al and is narrowed by adding In.

FIG. 1 is a vertical cross-sectional view showing a Schottky barrier diode 1 a in the first embodiment.

The Schottky barrier diode la is a vertical Schottky barrier diode and has a first Ga₂O₃-based crystal layer 10, a second Ga₂O₃-based crystal layer 11 laminated on the first Ga₂O₃-based crystal layer 10, an anode electrode 12 connected to the second Ga₂O₃-based crystal layer 11, and a cathode electrode 13 connected to the first Ga₂O₃-based crystal layer 10.

The first Ga₂O₃-based crystal layer 10 is formed of an n⁺ type Ga₂O₃-based single crystal containing a Group IV element, such as Si or Sn, as a donor. The donor concentration in the first Ga₂O₃-based crystal layer 10 is, e.g., 1×10¹⁷ to 1×10²⁰ cm⁻³. The thickness of the first Ga₂O₃-based crystal layer 10 is, e.g., 0.5 to 1000 μm.

In a typical configuration of the Schottky barrier diode 1 a, the first Ga₂O₃-based crystal layer 10 is a Ga₂O₃-based substrate. The orientation of the principal plane of the first Ga₂O₃-based crystal layer 10 is, e.g., (010), (001) or (−201).

The second Ga₂O₃-based crystal layer 11 is a layer formed on the first Ga₂O₃-based crystal layer 10 by epitaxial crystal growth and is formed of a Ga₂O₃-based single crystal containing an unintentionally doped donor. The unintentionally doped donor here includes impurities as well as defects such as oxygen vacancy. The concentration of the unintentionally doped donor is, e.g., not more than 1×10¹⁸ cm⁻³. The thickness of the second Ga₂O₃-based crystal layer 11 is, e.g., 0.1 to 100 μm.

The second Ga₂O₃-based crystal layer 11 also contains an intentionally doped N which compensates the unintentionally doped donor. To reduce electron concentration, the N concentration in the second Ga₂O₃-based crystal layer 11 is preferably not more than the concentration of the unintentionally doped donor. N is doped during crystal growth of the second Ga₂O₃-based crystal layer 11 (in-situ doping), hence, the entire second Ga₂O₃-based crystal layer 11 is the N-doped region. However, when, e.g., a Group IV element as a donor, such as Si or Sn, is intentionally doped simultaneously with addition of N, the N concentration may be higher than the concentration of the unintentionally doped donor.

The second Ga₂O₃-based crystal layer 11 is formed by, e.g., Molecular-beam epitaxy method (MBE method) performed using a Ga metal and an ozone gas made from an O₂—N₂ gas mixture.

The anode electrode 12 has, e.g., a stacked structure of Pt/Ti/Au and is in Schottky contact with the second Ga₂O₃-based crystal layer 11.

The cathode electrode 13 has, e.g., a stacked structure of Ti/Au and is in ohmic contact with the first Ga₂O₃-based crystal layer 10.

In the Schottky barrier diode la, an energy barrier between the anode electrode 12 and the second Ga₂O₃-based crystal layer 11 as viewed from the second Ga₂O₃-based crystal layer 11 is lowered by applying forward voltage between the anode electrode 12 and the cathode electrode 13 (positive potential on the anode electrode 12 side), allowing a current flow from the anode electrode 12 to the cathode electrode 13. Thus, the second Ga₂O₃-based crystal layer 11, which is entirely formed of the N-doped region, serves as a current path. On the other hand, when reverse voltage is applied between the anode electrode 12 and the cathode electrode 13 (negative potential on the anode electrode 12 side), the current flow is interrupted by the Schottky barrier.

FIG. 2 is a vertical cross-sectional view showing a Schottky barrier diode 1 b in the first embodiment. The Schottky barrier diode 1 b is different from the Schottky barrier diode 1 a in that it has a field-plate structure.

In the Schottky barrier diode 1 b, an insulating film 14 formed of SiO₂, etc., is provided on an upper surface of the second Ga₂O₃-based crystal layer 11 along the periphery of an anode electrode 16 which is arranged so that the edge thereof rides on the insulating film 14.

By providing such field-plate structure, it is possible to prevent the electric field from concentrating at the edge portion of the anode electrode 16. The insulating film 14 also serves as a passivation film for preventing a surface leakage current which flows along the upper surface of the second Ga₂O₃-based crystal layer 11.

FIG. 3 is a vertical cross-sectional view showing a Schottky barrier diode 1 c in the first embodiment.

The Schottky barrier diode 1 c is different from the Schottky barrier diode 1 b in that it has a guard ring structure. In the Schottky barrier diode 1 c, an N-doped region 101 as a guard ring is formed in a second Ga₂O₃-based crystal layer 15 in the vicinity of the upper surface thereof. In other words, the N-doped region 101 is formed in a part of the second Ga₂O₃-based crystal layer 15.

The second Ga₂O₃-based crystal layer 15 is formed of an n⁻ type Ga₂O₃-based single crystal containing a Group IV element, such as Si or Sn, as a donor. The donor concentration in the second Ga₂O₃-based crystal layer 15 is, e.g., not more than 1×10¹⁸ cm⁻³. The thickness of the second Ga₂O₃-based crystal layer 15 is, e.g., 0.1 to 100 μm.

The N-doped region 101 is formed by, e.g., selectively implanting N ions into the upper surface of the second Ga₂O₃-based crystal layer 15 in a region partially overlapping the anode electrode 16. The N concentration in the N-doped region 101 is higher than the donor concentration in the second Ga₂O₃-based crystal layer 15. By providing such a guard ring structure, it is possible to reduce concentration of the electric field at the edge portion of the anode electrode 16.

Second Embodiment

The second embodiment is an embodiment of a vertical MOSFET (Metal-Oxide-Semiconductor Field Effect Transistor) as a semiconductor device having a Ga₂O₃-based crystal layer in which an N-doped region is formed.

FIG. 4 is a vertical cross-sectional view showing a vertical MOSFET 2 a in the second embodiment.

The vertical MOSFET 2 a has a first Ga₂O₃-based crystal layer 20, a second Ga₂O₃-based crystal layer 21 laminated on the first Ga₂O₃-based crystal layer 20, a gate electrode 24 formed on the second Ga₂O₃-based crystal layer 21 via a gate insulating film 25, n⁺ regions 202 formed in the second Ga₂O₃-based crystal layer 21 in the vicinity of the upper surface on both sides of the gate electrode 24, p⁺ regions 203 formed on the outer side of the n⁺ regions 202, an N-doped region 201 surrounding the n⁺ regions 202 and the p⁺ regions 203, a source electrode 22 connected to the n⁺ regions 202 and the p⁺ regions 203, and a drain electrode 23 formed on a surface of the first Ga₂O₃-based crystal layer 20 opposite to the second Ga₂O₃-based crystal layer 21.

The vertical MOSFET 2 a is a vertical enhancement-mode (normally-off) MOSFET. When voltage of over a threshold is applied to the gate electrode 24, an inversion channel is formed in the N-doped region 201 under the gate electrode 24, allowing a current flow from the drain electrode 23 to the source electrode 22. That is, the N-doped region 201 includes a channel region (a region in which a channel is formed).

The first Ga₂O₃-based crystal layer 20 is formed of an n⁺ type Ga₂O₃-based single crystal containing a Group IV element, such as Si or Sn, as a donor. The donor concentration in the first Ga₂O₃-based crystal layer 20 is, e.g., 1×10¹⁷ to 1×10²⁰ cm⁻³. The thickness of the first Ga₂O₃-based crystal layer 20 is, e.g., 0.5 to 1000 μm.

In a typical configuration of the vertical MOSFET 2 a, the first Ga₂O₃-based crystal layer 20 is a Ga₂O₃-based substrate. The orientation of the principal plane of the first Ga₂O₃-based crystal layer 20 is, e.g., (010), (001) or (−201).

The second Ga₂O₃-based crystal layer 21 is formed of an n⁻ type Ga₂O₃-based single crystal containing a Group IV element, such as Si or Sn, as a donor. The donor concentration in the second Ga₂O₃-based crystal layer 21 is, e.g., not more than 1×10¹⁸ cm⁻³. The thickness of the second Ga₂O₃-based crystal layer 21 is, e.g., 1 to 100 μm.

The source electrode 22, the drain electrode 23 and the gate electrode 24 are formed of, e.g., Ti/Au. The gate insulating film 25 is formed of an insulating material such as SiO₂.

The n⁺ region 202 is a region with a high n-type dopant concentration formed in the second Ga₂O₃-based crystal layer 21 by ion implantation, etc. The p⁺ region 203 is a region with a high p-type dopant concentration formed by burying of a p-type material or ion implantation, etc., into the second Ga₂O₃-based crystal layer 21.

The N-doped region 201 is a region which is formed by ion implantation, etc., and surrounds the n⁺ regions 202 and the p⁺ regions 203. In other words, the N-doped region 201 is formed in a part of the second Ga₂O₃-based crystal layer 21. The N concentration in the N-doped region 201 is higher than the donor concentration in the second Ga₂O₃-based crystal layer 21 (the region except the n⁺ regions 202 and the p⁺ regions 203).

FIG. 5 is a vertical cross-sectional view showing a vertical MOSFET 2 b in the second embodiment. The vertical MOSFET 2 b is different from the vertical MOSFET 2 a in that it is a vertical trench MOSFET with the gate electrode embedded in the second Ga₂O₃-based crystal layer.

In the vertical MOSFET 2 b, a gate electrode 26 is covered with a gate insulating film 27 and is embedded in the second Ga₂O₃-based crystal layer 21, and the N-doped region 201, the n⁺ regions 202 and the p⁺ regions 203 are located on both sides of the gate electrode 26.

The vertical MOSFET 2 b is a vertical enhancement-mode MOSFET. When voltage of over a threshold is applied to the gate electrode 26, an inversion channel is formed in the N-doped region 201 on the lateral side of the gate electrode 26, allowing a current flow from the drain electrode 23 to the source electrode 22. That is, the N-doped region 201 includes a channel region.

FIG. 6 is a vertical cross-sectional view showing a vertical MOSFET 2 c in the second embodiment. The vertical MOSFET 2 c is different from the vertical MOSFET 2 a in that it is a vertical depletion-mode (normally-on) MOSFET in which a current blocking layer is formed.

In the vertical MOSFET 2 c, n⁺regions 205 are formed in the second Ga₂O₃-based crystal layer 21 in the vicinity of the upper surface on both sides of the gate electrode 24, and an N-doped region 204 as a current blocking region having an opening region is formed in a portion of the second Ga₂O₃-based crystal layer 21 below the n⁺ regions 205.

The n⁺ region 205 is a region with a high n-type dopant concentration formed in the second Ga₂O₃-based crystal layer 21 by ion implantation, etc.

The N-doped region 204 is formed in a portion below the n⁺ regions 205 by ion implantation, etc. A region 204 a located below the gate electrode 24 and surrounded by the N-doped region 204 is an opening region of the current blocking region and serves as a current path. That is, the N-doped region 204 is formed in a part of the second Ga₂O₃-based crystal layer 21. The N concentration in the N-doped region 204 is higher than the donor concentration in the second Ga₂O₃-based crystal layer 21 (the region except the n⁺ regions 205).

The vertical MOSFET 2 c is a vertical depletion-mode MOSFET, as described above. The current can flow from the drain electrode 23 to the source electrode 22 in a state that no voltage or voltage of over a threshold is applied to the gate electrode 24, but when voltage of less than the threshold is applied to the gate electrode 24, the channel is partially closed, allowing the current to be turned off.

Third Embodiment

The third embodiment is an embodiment of a lateral MOSFET as a semiconductor device having a Ga₂O₃-based crystal layer in which an N-doped region is formed.

FIG. 7 is a vertical cross-sectional view showing a lateral MOSFET 3 a in the third embodiment.

The lateral MOSFET 3 a has a first Ga₂O₃-based crystal layer 30, a second Ga₂O₃-based crystal layer 31 laminated on the first Ga₂O₃-based crystal layer 30, a source electrode 32 and a drain electrode 33 which are formed on the second Ga₂O₃-based crystal layer 31, a gate electrode 34 formed on the second Ga₂O₃-based crystal layer 31 via a gate insulating film 35 in a region between the source electrode 32 and the drain electrode 33, n⁺ regions 302 formed in the second Ga₂O₃-based crystal layer 31 in the vicinity of the upper surface on both sides of the gate electrode 34 and respectively connected to the source electrode 32 and the drain electrode 33, and an N-doped region 301 formed in the second Ga₂O₃-based crystal layer 31 between the n⁺ regions 302 and the first Ga₂O₃-based crystal layer 30 so as to be continuous in an in-plane direction.

The lateral MOSFET 3 a is a lateral depletion-mode MOSFET. The current can flow from the drain electrode 33 to the source electrode 32 in a state that no voltage is applied to the gate electrode 34, but when voltage of less than the threshold is applied to the gate electrode 34, a depletion layer expands and this causes the channel between the two n⁺ regions 302 to be narrowed, resulting in interruption of the current flow.

The first Ga₂O₃-based crystal layer 30 is a semi-insulating layer to which an acceptor impurity such as Fe is intentionally doped at a concentration higher than the donor concentration. Resistivity of the first Ga₂O₃-based crystal layer 30 is, e.g., larger than 1×10¹⁰ Ωcm. The thickness of the first Ga₂O₃-based crystal layer 30 is, e.g., 0.5 to 1000 μm.

In a typical configuration of the lateral MOSFET 3 a, the first Ga₂O₃-based crystal layer 30 is a Ga₂O₃-based substrate. The orientation of the principal plane of the first Ga₂O₃-based crystal layer 30 is, e.g., (010), (001) or (−201).

The second Ga₂O₃-based crystal layer 31 is formed of an n⁻ type Ga₂O₃-based single crystal containing a Group IV element, such as Si or Sn, as a donor. The donor concentration in the second Ga₂O₃-based crystal layer 31 is, e.g., 1×10¹⁶ to 5×10¹⁹ cm⁻³. The thickness of the second Ga₂O₃-based crystal layer 31 is, e.g., 0.02 to 100 μm. The source electrode 32, the drain electrode 33 and the gate electrode 34 are formed of, e.g., Ti/Au. The gate insulating film 35 is formed of an insulating material such as SiO₂.

The n⁺ region 302 is a region with a high n-type dopant concentration formed in the second Ga₂O₃-based crystal layer 31 by ion implantation, etc.

The N-doped region 301 is formed by ion implantation, etc., at a position blocking between a channel, which is formed between the two n⁺ regions 302, and an interface formed between the second Ga₂O₃-based crystal layer 31 and the first Ga₂O₃-based crystal layer 30. In other words, the N-doped region 301 is formed between the channel region, which is formed in the second Ga₂O₃-based crystal layer 31 and is a part of the second Ga₂O₃-based crystal layer 31, and a bottom surface of the second Ga₂O₃-based crystal layer 31. Thus, the N-doped region 301 can prevent a leakage current which flows through the interface between the second Ga₂O₃-based crystal layer 31 and the first Ga₂O₃-based crystal layer 30. The N concentration in the N-doped region 301 is higher than the donor concentration in the second Ga₂O₃-based crystal layer 31 (the region except the n⁺ regions 302).

FIG. 8 is a vertical cross-sectional view showing a lateral MOSFET 3 b in the third embodiment. The lateral MOSFET 3 b is different from the lateral MOSFET 3 a in that the N-doped region is formed in the entire second Ga₂O₃-based crystal layer.

A second Ga₂O₃-based crystal layer 36 of the lateral MOSFET 3 b is a layer formed on the first Ga₂O₃-based crystal layer 30 by epitaxial crystal growth and is formed of a Ga₂O₃-based single crystal containing an unintentionally doped donor. The concentration of the unintentionally doped donor is, e.g., not more than 1×10¹⁸ cm⁻³. The thickness of the second Ga₂O₃-based crystal layer 36 is, e.g., 0.02 to 100 μm.

The second Ga₂O₃-based crystal layer 36 also contains an intentionally doped N which compensates the unintentionally doped donor. To reduce electron concentration, the N concentration in the second Ga₂O₃-based crystal layer 36 is preferably not more than the concentration of the unintentionally doped donor. N is doped during crystal growth of the second Ga₂O₃-based crystal layer 36, hence, the entire second Ga₂O₃-based crystal layer 36 is the N-doped region. Alternatively, N may be doped to the second Ga₂O₃-based crystal layer 36 by ion implantation. When, e.g., a Group IV element as a donor, such as Si or Sn, is intentionally doped simultaneously with addition of N, the N concentration may be higher than the concentration of the unintentionally doped donor.

The lateral MOSFET 3 b is a lateral depletion-mode MOSFET. The current can flow from the drain electrode 33 to the source electrode 32 in a state that no voltage is applied to the gate electrode 34, but when voltage of not more than the threshold is applied to the gate electrode 34, a depletion layer expands and this causes the channel between the two n⁺ regions 302 to be narrowed, resulting in interruption of the current flow. That is, the N-doped region formed in the entire second Ga₂O₃-based crystal layer 36 includes a channel region.

FIG. 9 is a vertical cross-sectional view showing a lateral MOSFET 3 c in the third embodiment. The lateral MOSFET 3 c is different from the lateral MOSFET 3 b in that it is an enhancement-mode device.

A second Ga₂O₃-based crystal layer 37 of the lateral MOSFET 3 c is a layer formed on the first Ga₂O₃-based crystal layer 30 by epitaxial crystal growth and is formed of a Ga₂O₃-based single crystal containing an unintentionally doped donor. The concentration of the unintentionally doped donor is, e.g., not more than 1×10¹⁸ cm⁻³. The thickness of the second Ga₂O₃-based crystal layer 37 is, e.g., 0.02 to 100 μm.

The second Ga₂O₃-based crystal layer 37 also contains an intentionally doped N which compensates the unintentionally doped donor. The N concentration in the second Ga₂O₃-based crystal layer 37 is preferably higher than the concentration of the unintentionally doped donor. N is doped during crystal growth of the second Ga₂O₃-based crystal layer 37, hence, the entire second Ga₂O₃-based crystal layer 37 is the N-doped region. Alternatively, N may be doped to the second Ga₂O₃-based crystal layer 37 by ion implantation.

A gate electrode 38 of the lateral MOSFET 3 c overlaps with, or is located very close to, end portions of the n⁺ regions 302 so that a continuous channel region is formed between the source electrode 32 and the drain electrode 33.

The lateral MOSFET 3 c is a lateral enhancement-mode MOSFET. When voltage of over a threshold is applied to the gate electrode 38, a channel is formed between the two n⁺ regions 302 in the vicinity of the upper surface of the second Ga₂O₃-based crystal layer 37, allowing a current flow from the drain electrode 33 to the source electrode 32. That is, the N-doped region formed in the entire second Ga₂O₃-based crystal layer 37 includes a channel region.

FIG. 10 is a vertical cross-sectional view showing a lateral MOSFET 3 d in the third embodiment. The lateral MOSFET 3 d is different from the lateral MOSFET 3 c in that the N-doped region is formed only in a portion of the second Ga₂O₃-based crystal layer on the upper side.

An N-doped region 303 of the lateral MOSFET 3 d is formed in the second Ga₂O₃-based crystal layer 31 by ion implantation, etc., in an upper region including the n⁺ regions 302. That is, the N-doped region 303 is formed in a part of the second Ga₂O₃-based crystal layer 31. The N concentration in the N-doped region 303 is higher than the donor concentration in the second Ga₂O₃-based crystal layer 31 (the region except the n⁺ regions 302).

The lateral MOSFET 3 d is a lateral enhancement-mode MOSFET, in the same manner as the lateral MOSFET 3 c. When voltage of over a threshold is applied to the gate electrode 38, a channel is formed between the two n⁺ regions 302 in the vicinity of the upper surface of the second Ga₂O₃-based crystal layer 31 (the N-doped region 303), allowing a current flow from the drain electrode 33 to the source electrode 32. That is, the N-doped region 303 includes a channel region.

Fourth Embodiment

The fourth embodiment is an embodiment of a lateral MESFET (Metal-Semiconductor Field Effect Transistor) as a semiconductor device having a Ga₂O₃-based crystal layer in which an N-doped region is formed.

FIG. 11 is a vertical cross-sectional view showing a MESFET 4 a in the fourth embodiment.

The MESFET 4 a has a first Ga₂O₃-based crystal layer 40, a second Ga₂O₃-based crystal layer 41 laminated on the first Ga₂O₃-based crystal layer 40, a source electrode 42 and a drain electrode 43 which are formed on the second Ga₂O₃-based crystal layer 41, a gate electrode 44 formed on the second Ga₂O₃-based crystal layer 41 in a region between the source electrode 42 and the drain electrode 43, n⁺ regions 402 formed in the second Ga₂O₃-based crystal layer 41 in the vicinity of the upper surface on both sides of the gate electrode 44 and respectively connected to the source electrode 42 and the drain electrode 43, and an N-doped region 401 formed in the second Ga₂O₃-based crystal layer 41 between the n⁺ regions 402 and the first Ga₂O₃-based crystal layer 40 so as to be continuous in an in-plane direction.

The gate electrode 44 is in Schottky contact with the upper surface of the second Ga₂O₃-based crystal layer 41 and a depletion layer is formed in the second Ga₂O₃-based crystal layer 41 under the gate electrode 44. The MESFET 4 a functions as either a depletion-mode transistor or an enhancement-mode transistor depending on the thickness of the depletion region.

The first Ga₂O₃-based crystal layer 40 is a semi-insulating layer to which an acceptor impurity such as Fe is intentionally doped at a concentration higher than the donor concentration. Resistivity of the first Ga₂O₃-based crystal layer 40 is, e.g., not less than 1×10¹⁰ Ωcm. The thickness of the first Ga₂O₃-based crystal layer 40 is, e.g., 0.5 to 1000 μm.

In a typical configuration of the MESFET 4 a, the first Ga₂O₃-based crystal layer 40 is a Ga₂O₃-based substrate. The orientation of the principal plane of the first Ga₂O₃-based crystal layer 40 is, e.g., (010), (001) or (−201).

The second Ga₂O₃-based crystal layer 41 is formed of an n⁻ type Ga₂O₃-based single crystal containing a Group IV element, such as Si or Sn, as a donor. The donor concentration in the second Ga₂O₃-based crystal layer 41 is, e.g., 1×10¹⁶ to 5×10¹⁹ cm⁻³. The thickness of the second Ga₂O₃-based crystal layer 41 is, e.g., 0.02 to 100 μm.

The source electrode 42 and the drain electrode 43 are formed of, e.g., Ti/Au. The gate electrode 44 is formed of, e.g., Pt/Ti/Au.

The n⁺ region 402 is a region with a high n-type dopant concentration formed in the second Ga₂O₃-based crystal layer 41 by ion implantation, etc.

The N-doped region 401 is formed by ion implantation, etc., at a position blocking between a channel, which is formed between the two n⁺ regions 402, and an interface formed between the second Ga₂O₃-based crystal layer 41 and the first Ga₂O₃-based crystal layer 40. In other words, the N-doped region 401 is formed between the channel region, which is formed in the second Ga₂O₃-based crystal layer 41 and is a part of the second Ga₂O₃-based crystal layer 41, and a bottom surface of the second Ga₂O₃-based crystal layer 41. Thus, the N-doped region 401 can prevent a leakage current which flows through the interface between the second Ga₂O₃-based crystal layer 41 and the first Ga₂O₃-based crystal layer 40. The N concentration in the N-doped region 401 is higher than the donor concentration in the second Ga₂O₃-based crystal layer 41 (the region except the n⁺ regions 402).

FIG. 12 is a vertical cross-sectional view showing a MESFET 4 b in the fourth embodiment. The MESFET 4 b is different from the MESFET 4 a in that the N-doped region is formed in the entire second Ga₂O₃-based crystal layer.

A second Ga₂O₃-based crystal layer 45 of the MESFET 4 b is a layer formed on the first Ga₂O₃-based crystal layer 40 by epitaxial crystal growth and is formed of a Ga₂O₃-based single crystal containing an unintentionally doped donor. The concentration of the unintentionally doped donor is, e.g., not more than 1×10¹⁸ cm ⁻³. The thickness of the second Ga₂O₃-based crystal layer 45 is, e.g., 0.02 to 100 μm.

The second Ga₂O₃-based crystal layer 45 also contains an intentionally doped N which compensates the unintentionally doped donor. To reduce electron concentration, the N concentration in the second Ga₂O₃-based crystal layer 45 is preferably not more than the concentration of the unintentionally doped donor. N is doped during crystal growth of the second Ga₂O₃-based crystal layer 45, hence, the entire second Ga₂O₃-based crystal layer 45 is the N-doped region. Alternatively, N may be doped to the second Ga₂O₃-based crystal layer 45 by ion implantation. When, e.g., a Group IV element as a donor, such as Si or Sn, is intentionally doped simultaneously with addition of N, the N concentration may be higher than the concentration of the unintentionally doped donor.

The gate electrode 44 is in Schottky contact with the upper surface of the second Ga₂O₃-based crystal layer 45 and a depletion layer is formed in the second Ga₂O₃-based crystal layer 45 under the gate electrode 44. The MESFET 4 b functions as either a depletion-mode transistor or an enhancement-mode transistor depending on the thickness of the depletion region.

Effects of the Embodiments

According to the first to fourth embodiments, it is possible to increase resistance of Ga₂O₃-based crystal or to form a p-type region by using N which has not been known as an acceptor in the Ga₂O₃-based crystal. It is also possible to provide a semiconductor device having a Ga₂O₃-based crystal layer doped with such N.

EXAMPLE 1

Experiments confirmed that N doped to Ga₂O₃-based crystal acts as an acceptor.

FIG. 13 is a vertical cross-sectional view showing a sample device 5 used in experiments in Example 1. The sample device 5 has a Ga₂O₃ single crystal substrate 50 containing an unintentionally doped donor, an n⁺ type Ga₂O₃ single crystal layer 51 laminated on the Ga₂O₃ single crystal substrate 50, an N-doped region 501 formed in the Ga₂O₃ single crystal substrate 50, an n⁺region 502 formed in the Ga₂O₃ single crystal substrate 50 in the vicinity of the upper surface (a surface opposite to the Ga₂O₃ single crystal layer 51), an electrode 52 having a Ti/Au laminated structure and ohmic-connected to the n⁺ region 502 of the Ga₂O₃ single crystal substrate 50, and an electrode 53 having a Ti/Au laminated structure and ohmic-connected to the Ga₂O₃ single crystal layer 51.

The concentration of the unintentionally doped donor in the Ga₂O₃ single crystal substrate 50 is about 3×10¹⁷ cm⁻³. The orientation of the principal plane of the Ga₂O₃ single crystal substrate 50 is (001).

The N-doped region 501 was formed by ion implantation of N into a layer-shaped region of the Ga₂O₃ single crystal substrate 50 located at a depth of 600 to 700 nm from the upper surface under the implantation conditions of 4×10¹³ cm⁻² at 480 keV. In addition, after the ion implantation, annealing was performed in an N₂ atmosphere at 800 to 1200° C. for 30 minutes to activate the doped N and to recover damage of the Ga₂O₃ single crystal substrate 50 caused by the ion implantation. The maximum concentration of N in the N-doped region 501 was 1.5×10¹⁸ cm⁻³.

The n⁺ region 502 was formed by ion implantation of Si into the Ga₂O₃ single crystal substrate 50 in the vicinity of the upper surface. After the ion implantation, annealing was performed in an N₂ atmosphere at 800° C. for 30 minutes to activate the doped Si.

Voltage was applied between the electrode 52 and the electrode 53 of the sample device 5 and the magnitude of vertical leakage current was measured. The result confirmed that N in the N-doped region 501 is acting as an acceptor.

FIG. 14 is a graph showing measured leakage characteristics of the sample device 5. FIG. 14 shows that leakage current decreases with an increase in an annealing temperature from 800° C. to 1200° C. With an annealing temperature of 1200° C., the minimum value of leakage current at a voltage of 200V was 1 to 10 μA/cm². This confirmed that N in the N-doped region 501 is acting as an acceptor.

EXAMPLE 2

The Schottky barrier diode la in the first embodiment was made, and a relation between the N concentration in the second Ga₂O₃-based crystal layer 11 entirely formed of the N-doped region and electrical conduction properties of the Schottky barrier diode 1 a.

In Example 2, an Sn-doped n⁺ type Ga₂O₃ single crystal substrate having a (001) plane as a principal plane was used as the first Ga₂O₃-based crystal layer 10. Si with a concentration of 5×10¹⁹ cm⁻³ was ion-implanted into the back surface of the first Ga₂O₃-based crystal layer 10 to form a 150 nm deep box profile for an ohmic contact with the cathode electrode 13.

Then, a 2.6 μm-thick N-doped Ga₂O₃ single crystal was homoepitaxially grown on the first Ga₂O₃-based crystal layer 10 by MBE using a Ga metal and an ozone gas made from an O₂—N₂ gas mixture, thereby forming the second Ga₂O₃-based crystal layer 11.

Then, a 200 μm-diameter circular electrode having a Pt/Ti/Au stacked structure was formed as the anode electrode 12. An electrode having a Ti/Au stacked structure was formed as the cathode electrode 13.

Firstly, to make sure that the second Ga₂O₃-based crystal layer 11 was doped with N, secondary-ion mass spectrometry (SIMS) measurement was performed on a sample device without the anode electrode 12 and the cathode electrode 13.

FIGS. 15A, 15B and 15C show SIMS profiles of N in the second Ga₂O₃-based crystal layer 11 when an N₂ gas concentration in an O₂—N₂ gas mixture used for growth of the second Ga₂O₃-based crystal layer 11 is respectively 0 vol %, 0.04 vol % and 0.4 vol %. In the drawings, a profile shown in a region shallower than the depth indicated by a dotted line (a region on the left side of the dotted line) is from the second Ga₂O₃-based crystal layer 11, and a profile shown in a region deeper than the depth indicated by the dotted line (a region on the right side of the dotted line) is from the first Ga₂O₃-based crystal layer 10.

As shown in FIGS. 15A, 15B and 15C, the N concentration in the second Ga₂O₃-based crystal layer 11, when the N₂ gas concentration in the O₂—N₂ gas mixture is 0 vol %, 0.04 vol % and 0.4 vol %, was respectively 2.5×10¹⁶ cm⁻³, 3.4×10¹⁶ cm⁻³ and 1.5×10¹⁷ cm⁻³. This shows that it is possible to dope N to Ga₂O₃-based crystal and it is also possible to control the N concentration in the Ga₂O₃-based crystal by adjusting the N concentration in a source gas of ozone.

Next, electrical conduction properties of the Schottky barrier diode la were measured using a sample having the anode electrode 12 and the cathode electrode 13.

FIGS. 16A, 16B and 16C are graphs showing electrical conduction properties of the Schottky barrier diode la when the N₂ gas concentration in the O₂—N₂ gas mixture used for growth of the second Ga₂O₃-based crystal layer 11 is respectively 0 vol %, 0.04 vol % and 0.4 vol %.

All of the Schottky barrier diodes 1 a in FIGS. 16A, 16B and 16C exhibit n-type rectification properties in that a large amount of current flows only when the anode voltage is positive.

FIG. 17 is a graph showing a relation between the N₂ gas concentration in the O₂—N₂ gas mixture used for growth of the second Ga₂O₃-based crystal layer 11 and forward current density when an anode voltage of the Schottky barrier diode 1 a is 6V, which is derived from the current characteristics shown in FIGS. 16A, 16B and 16C.

The forward current density shown in FIG. 17, when the N₂ gas concentration in the O₂—N₂ gas mixture is 0 vol %, 0.04 vol % and 0.4 vol %, is respectively 4.88×10⁻⁶, 5.70×10⁻⁷ and 8.76×10⁻⁹ A/cm².

FIG. 17 shows that the current exponentially decreases with an increase in the N₂ gas concentration. This shows that the intentionally doped N in the second Ga₂O₃-based crystal layer 11 contributes to increase resistance of the second Ga₂O₃-based crystal layer 11.

Although the embodiments and Examples of the invention have been described, the invention is not intended to be limited to the embodiments and Examples, and the various kinds of modifications can be implemented without departing from the gist of the invention. In addition, the constituent elements in the embodiment and Examples can be arbitrarily combined without departing from the gist of the invention.

In addition, the invention according to claims is not to be limited to the embodiments and Examples described above. Further, it should be noted that all combinations of the features described in the embodiments and Examples are not necessary to solve the problem of the invention.

INDUSTRIAL APPLICABILITY

Provided is a Ga₂O₃-based semiconductor device which has a Ga₂O₃-based crystal layer doped with a novel acceptor impurity.

REFERENCE SIGNS LIST

1 a, 1 b, 1 c SCHOTTKY BARRIER DIODE

2 a, 2 b, 2 c VERTICAL MOSFET

3 a, 3 b, 3 c, 3 d LATERAL MOSFET 3 a

4 a, 4 b MESFET 4 b

10, 20, 30, 40 FIRST Ga₂O₃-BASED CRYSTAL LAYER

11, 15, 21, 31, 36, 41, 45 SECOND Ga₂O₃-BASED CRYSTAL LAYER

101, 201, 204, 301, 303, 401 N-DOPED REGION 

1. A Ga₂O₃-based semiconductor device, comprising: a Ga₂O₃-based crystal layer comprising a donor; and an N-doped region formed in at least a part of the Ga₂O₃-based crystal layer.
 2. The Ga₂O₃-based semiconductor device according to claim 1, wherein the N-doped region comprises N at a higher concentration than the donor.
 3. The Ga₂O₃-based semiconductor device according to claim 1, wherein the N-doped region is formed in a part of the Ga₂O₃-based crystal layer.
 4. The Ga₂O₃-based semiconductor device according to claim 1, wherein the donor is unintentionally doped to the Ga₂O₃-based crystal layer, and the N-doped region comprises N at a concentration not more than the concentration of the donor.
 5. The Ga₂O₃-based semiconductor device according to claim 1, comprising a vertical Schottky barrier diode in which the N-doped region is a current path or a guard ring.
 6. The Ga₂O₃-based semiconductor device according to claim 1, comprising a vertical MOSFET in which the N-doped region comprises a channel region or is a current blocking region comprising an opening region as a current path.
 7. The Ga₂O₃-based semiconductor device according to claim 1, comprising a lateral MOSFET in which the N-doped region comprises a channel region or is located between a channel region in the Ga₂O₃-based crystal layer and a bottom surface of the Ga₂O₃-based crystal layer.
 8. The Ga₂O₃-based semiconductor device according to claim 1, comprising a MESFET in which the N-doped region comprises a channel region or is located between a channel region in the Ga₂O₃-based crystal layer and a bottom surface of the Ga₂O₃-based crystal layer.
 9. The Ga₂O₃-based semiconductor device according to claim 2, wherein the N-doped region is formed in a part of the Ga₂O₃-based crystal layer.
 10. The Ga₂O₃-based semiconductor device according to claim 2, comprising a vertical Schottky barrier diode in which the N-doped region is a current path or a guard ring.
 11. The Ga₂O₃-based semiconductor device according to claim 4, comprising a vertical Schottky barrier diode in which the N-doped region is a current path or a guard ring.
 12. The Ga₂O₃-based semiconductor device according to claim 2, comprising a vertical MOSFET in which the N-doped region comprises a channel region or is a current blocking region comprising an opening region as a current path.
 13. The Ga₂O₃-based semiconductor device according to claim 2, comprising a lateral MOSFET in which the N-doped region comprises a channel region or is located between a channel region in the Ga₂O₃-based crystal layer and a bottom surface of the Ga₂O₃-based crystal layer.
 14. The Ga₂O₃-based semiconductor device according to claim 4, comprising a lateral MOSFET in which the N-doped region comprises a channel region or is located between a channel region in the Ga₂O₃-based crystal layer and a bottom surface of the Ga₂O₃-based crystal layer.
 15. The Ga₂O₃-based semiconductor device according to claim 2, comprising a MESFET in which the N-doped region comprises a channel region or is located between a channel region in the Ga₂O₃-based crystal layer and a bottom surface of the Ga₂O₃-based crystal layer.
 16. The Ga₂O₃-based semiconductor device according to claim 4, comprising a MESFET in which the N-doped region comprises a channel region or is located between a channel region in the Ga₂O₃-based crystal layer and a bottom surface of the Ga₂O₃-based crystal layer. 